Inorganic Chemistry
Purpose of Course showclose
Learning Outcomes showclose
- Describe nuclear charge and calculate effective nuclear charge in terms of Slater’s rules.
- Demonstrate an understanding of trends in the periodic table.
- Describe the bonding between atoms in terms of valence bond theory.
- Describe inorganic structures by using valence shell electron pair repulsion theory.
- Identify the nomenclature rules of coordination compounds.
- Demonstrate an understanding of crystal structures, lattice energies, and different types of unit cells.
- Explain the electronic structure of solids, the concept of band gap energy, and how this band gap determines the electronic properties (insulator, conductor, and semiconductor) of solid materials.
- Describe general trends in the reactivity of elements within Groups I through VII.
Course Requirements showclose
√ Have a computer.
√ Have continuous broadband Internet access
√ Have the ability/permission to install plug-ins or software (e.g., Adobe Reader or Flash).
√ Have the ability to download and save files and documents to a computer.
√ Have the ability to open Microsoft files and documents (.doc, .ppt., .xls, etc.).
√ Have competency in the English language.
√ Have read the Saylor Student Handbook.
√ Have completed CHEM101 and CHEM102.
Preliminary Information
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The Basics of General, Organic, and Biological Chemistry
You will be prompted to read sections of these books throughout the course. You may choose to download the texts in full now and skip to the appropriate section as prompted by the resource boxes below, or you can simply download the specific sections of the texts assigned as you progress through each resource box below.
Reading: The Basics of General, Organic, and Biological Chemistry (PDF)
Terms of Use: This text was adapted by The Saylor Foundation under a Creative Commons Attribution-NonCommercial-ShareAlike 3.0 License without attribution as requested by the work’s original creator or licensee. -
Unit 1: Introduction to Inorganic Chemistry
In this unit, you will learn the different parts of a hydrogen atom wavefunction and discover how wavefunctions relate to atomic orbitals and their relative energies. You will also learn how to determine the atomic term symbols from a given electronic configuration and use Hund’s rules to predict the electronic ground state. This unit ends with a comprehensive analysis of trends in the periodic table. You will learn how to rationalize the exceptions in these periodic trends.
Time Advisory show close
Learning Outcomes show close
- 1.1 Atomic Structure
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1.1.1 Review of the Hydrogen Atom and Its Wavefunctions
- Reading: University of Washington: Department of Chemistry: Dr. Philip Reid: “The Hydrogen Atom”
Link: University of Washington: Department of Chemistry: Dr. Philip Reid: “The Hydrogen Atom” (PDF)
Instructions: Please click the “handout_Lecture 18.pdf” link and then read this entire PDF about H-atom wavefunctions.
Terms of Use: Please respect the copyright and terms of use displayed on the webpage above.See a broken link? Please let us know!
- Lecture: Academic Earth: MIT OpenCourseWare: Dr. Sylvia Ceyer: “Hydrogen Atom Wavefunctions”
Link: Academic Earth: MIT OpenCourseWare: Dr. Sylvia Ceyer: “Hydrogen Atom Wavefunctions” (Adobe Flash)
Also available in:
iTunes or mp4
Instructions: Please watch this entire video (approximately 50 minutes) to learn how to determine the values of H-atom wavefunctions. Please read the lecture transcript and lecture notes (links for them are below the video) for greater clarification.
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- Reading: University of Washington: Department of Chemistry: Dr. Philip Reid: “The Hydrogen Atom”
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1.1.2 Review of Atomic Orbitals
- Lecture: Khan Academy's “Orbitals”
Link: Khan Academy's “Orbitals” (YouTube)
Also available in:
Adobe Flash
Instructions: Please watch this entire video (approximately 14 minutes) to learn the basics of atomic orbitals.
Terms of Use: This video is licensed under a Creative Commons Attribution-NonCommercial-ShareAlike 3.0 United States License. It is attributed to the Khan Academy.See a broken link? Please let us know!
- Lecture: Khan Academy's “Orbitals”
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1.2 Electronic Configurations
- Lecture: Khan Academy's “Electron Configurations”
Link: Khan Academy's “Electron Configurations” (Adobe Flash)
Also available in:
YouTube
Instructions: Please watch this entire video (approximately 10 minutes) to learn how to determine the electron configuration for s- and p-block elements.
Terms of Use: This video is licensed under a Creative Commons Attribution-NonCommercial-ShareAlike 3.0 United States License. It is attributed to the Khan Academy.See a broken link? Please let us know!
- Lecture: Khan Academy's “Electron Configurations 2”
Link: Khan Academy's “Electron Configurations 2” (YouTube)
Also available in:
Adobe Flash
Instructions: Please watch this entire video (approximately 10 minutes) to learn how to determine the electron configuration for d-block elements.
Terms of Use: This video is licensed under a Creative Commons Attribution-NonCommercial-ShareAlike 3.0 United States License. It is attributed to the Khan Academy.See a broken link? Please let us know!
- Lecture: Khan Academy's “Electron Configurations”
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1.2.1 Electron Spin and the Pauli Exclusion Principle
- Reading: UC Davis: ChemWiki: “Pauli Exclusion Principle”
Link: UC Davis: ChemWiki: “Pauli Exclusion Principle” (HTML or PDF)
Instructions: Please read this entire webpage.
Terms of Use: Please respect the copyright and terms of use displayed on the webpage above. You can download a PDF version by clicking “Make PDF” at the top of the page.
See a broken link? Please let us know!
- Reading: UC Davis: ChemWiki: “Pauli Exclusion Principle”
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1.2.2 Aufbau Principle
- Reading: UC Davis: ChemWiki: “Aufbau Principle”
Link: UC Davis: ChemWiki: “Aufbau Principle” (HTML or PDF)
Instructions: Please read this entire webpage.
Terms of Use: Please respect the copyright and terms of use displayed on the webpage above. You can download a PDF version by clicking “Make PDF” at the top of the page.See a broken link? Please let us know!
- Reading: University of Washington: Dr. Philip Reid: “Polyelectronic Atoms”
Link: University of Washington: Dr. Philip Reid: “Polyelectronic Atoms” (PDF)
Instructions: Please click the “handout_Lecture 19.pdf” link and then read this entire PDF about the Aufbau principle and periodic trends in ionization potential and electron affinity. This material also covers subunits 1.3.2 and 1.3.3.
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- Reading: UC Davis: ChemWiki: “Aufbau Principle”
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1.2.3 Atomic Term Symbols and Hund’s Rules
- Reading: UC Davis: ChemWiki: “Hund’s Rules”
Link: UC Davis: ChemWiki: “Hund’s Rules” (HTML or PDF)
Instructions: Please read this entire webpage.
Terms of Use: Please respect the copyright and terms of use displayed on the webpage above. You can download a PDF version by clicking “Make PDF” at the top of the page.See a broken link? Please let us know!
- Reading: UC Davis: ChemWiki: “Hund’s Rules”
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1.2.4 Shielding and Slater’s Rules
- Reading: UC Davis: ChemWiki: “Nuclear Charge and Orbital Size”
Link: UC Davis: ChemWiki: “Nuclear Charge and Orbital Size” (HTML or PDF)
Instructions: Please read this entire webpage, which provides information on Slater’s rules. Also, please attempt the exercises. You can download a PDF version by clicking “Make PDF” at the top of the page.
Terms of Use: Please respect the copyright and terms of use displayed on the webpage above.See a broken link? Please let us know!
- Reading: UC Davis: ChemWiki: “Penetration & Shielding”
Link: UC Davis: ChemWiki: “Penetration & Shielding” (HTML or PDF)
Instructions: Please read this entire webpage, which provides information on the concepts of penetration and shielding and the periodic trends due to penetration and shielding. Also, please attempt the problems. You can download a PDF version by clicking “Make PDF” at the top of the page.
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- Reading: UC Davis: ChemWiki: “Nuclear Charge and Orbital Size”
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1.3 The Periodic Table and Periodic Trends
- Reading: UC Davis: ChemWiki: “Periodic Trends”
Link: UC Davis: ChemWiki: “Periodic Trends” (HTML or PDF)
Instructions: Please read this entire webpage and also attempt the problems. This material also covers subunits 1.3.1 through 1.3.4. You can download a PDF version by clicking “Make PDF” at the top of the page.
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- Lecture: Khan Academy's “Other Periodic Table Trends”
Link: Khan Academy's “Other Periodic Table Trends” (YouTube)
Also available in:
Adobe Flash
Instructions: Please watch this entire video (approximately 16 minutes) to gain further insight into electronegativity, atomic radii, and the periodic table. This materials also covers subunits 1.3.1, 1.3.3, and 1.3.4.
Terms of Use: This video is licensed under a Creative Commons Attribution-NonCommercial-ShareAlike 3.0 United States License. It is attributed to the Khan Academy.See a broken link? Please let us know!
- Reading: UC Davis: ChemWiki: “Periodic Trends”
- 1.3.1 Atomic Size
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1.3.2 Ionization Potentials
- Lecture: Khan Academy's “Periodic Table Trends: Ionization Energy”
Link: Khan Academy's “Periodic Table Trends: Ionization Energy” (Adobe Flash)
Also available in:
YouTube
Instructions: Please watch this entire video (approximately 12 minutes) to gain further insight into ionization energy and the periodic table.
Terms of Use: This video is licensed under a Creative Commons Attribution-NonCommercial-ShareAlike 3.0 United States License. It is attributed to the Khan Academy.See a broken link? Please let us know!
- Lecture: Khan Academy's “Periodic Table Trends: Ionization Energy”
- 1.3.3 Electron Affinity
- 1.3.4 Electronegativity
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Unit 2: Complex Ions and Coordination Compounds
This unit will teach you the strengths and weaknesses of valence bond theory, crystal field theory, and molecular orbital theory in describing the bonding in coordination compounds and metal complex ions. In the process of discussing these theories, you will learn why certain complex ions have certain colors. The molecular orbital theory can explain why metal carbonyl compounds, such as [Co(CO)6], are often colorless, whereas halogen ligands often form complexes that are brightly colored, such as fluoride ions in the cobalt complex [CoF6]3-.
Time Advisory show close
Learning Outcomes show close
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2.1 Valence Bond Theory
- Reading: UC Davis: ChemWiki: “Valence Bond Theory”
Link: UC Davis: Chemwiki: “Valence Bond Theory” (HTML or PDF)
Instructions: Please read this entire webpage and also attempt the problems. Be sure to watch the embedded video and also click the links just before it. You can download a PDF version by clicking “Make PDF” at the top of the page.
Terms of Use: Please respect the copyright and terms of use displayed on the webpage above.See a broken link? Please let us know!
- Reading: University of Waterloo: Dr. Peter Chieh: “Valence Bond Theory and Hybrid Atomic Orbitals”
Link: University of Waterloo: Dr. Peter Chieh: “Valence Bond Theory and Hybrid Atomic Orbitals” (HTML)
Instructions: Please read this entire webpage and also attempt the problems offered.
Terms of Use: Please respect the copyright and terms of use displayed on the webpage above.See a broken link? Please let us know!
- Lecture: Academic Earth: MIT OpenCourseWare: Dr. Christopher Cummins: “Valence Bond Theory”
Link: Academic Earth: MIT OpenCourseWare: Dr. Christopher Cummins: “Valence Bond Theory” (Adobe Flash)
Also available in:
iTunes or mp4
Instructions: Please watch this entire video (approximately 44 minutes) for a greater understanding of valence bond theory.
Terms of Use: Please respect the copyright and terms of use displayed on the webpage above.See a broken link? Please let us know!
- Reading: UC Davis: ChemWiki: “Valence Bond Theory”
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2.2 Lewis/Electron Dot Structures
- Reading: Wikibooks: “Lewis Dot Structures”
Link: Wikibooks: “Lewis Dot Structures” (PDF)
Instructions: Please read this entire webpage for a basic understanding of Lewis dot structures.
Terms of Use: The article above is released under a Creative Commons Attribution-Share-Alike License 3.0 (HTML). You can find the original Wikibooks version of this article here (HTML).See a broken link? Please let us know!
- Reading: Boise State University: Dr. Richard Banks: “Bonding”
Link: Boise State University: Dr. Richard Banks: “Bonding” (HTML)
Instructions: Please read this entire webpage to learn about bond types. Also, please click the links to read the six “Drawing Electron-Dot Formulas” sections and attempt the practice problems.
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- Reading: Boise State University: Dr. Richard Banks: “Electron-Dot Formulas”
Link: Boise State University: Dr. Richard Banks: “Electron-Dot Formulas” (HTML)
Instructions: Please follow the tutorial links for tips on drawing Lewis dot structures.
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- Assessment: University of Florida: Dr. Philip J. Brucat: “Lewis Dot Structures (Multiple Choice)”
Link: University of Florida: Dr. Philip J. Brucat: “Lewis Dot Structures (Multiple Choice)” (HTML)
Instructions: This webpage presents a few exercises on drawing Lewis dot structures. Please follow the written instructions to conduct the exercises.
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- Reading: Wikibooks: “Lewis Dot Structures”
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2.3 Hybridization
- Reading: Boise State University: Dr. Richard Banks: “Bonding and Hybridization”
Link: Boise State University: Dr. Richard Banks: “Bonding and Hybridization” (HTML)
Instructions: Please read this entire webpage to learn about orbital hybridization, molecular shapes, and Lewis dot structures.
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- Reading: Boise State University: Dr. Richard Banks: “Bonding and Hybridization”
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2.4 VSEPR Theory
- Reading: Oklahoma State University: Dr. John I. Gelder: “Valence Shell Electron Pair Repulsion Theory”
Link: Oklahoma State University: Dr. John I. Gelder: “Valence Shell Electron Pair Repulsion Theory” (HTML)
Instructions: Please read this entire webpage and then click the electron-pair geometry links for details on bond angles and molecular geometries.
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See a broken link? Please let us know!
- Reading: Wikibooks: “VSEPR Theory”
Link: Wikibooks: “VSEPR Theory” (PDF)
Instructions: Please read this entire webpage to learn about VSPER theory and the AXE method.
Terms of Use: The article above is released under a Creative Commons Attribution-Share-Alike License 3.0 (HTML). You can find the original Wikibooks version of this article here (HTML).See a broken link? Please let us know!
- Reading: Oklahoma State University: Dr. John I. Gelder: “Valence Shell Electron Pair Repulsion Theory”
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2.5 Nomenclature
- Reading: UC Davis: ChemWiki: “Nomenclature of Coordination Complexes”
Link: UC Davis: ChemWiki: “Nomenclature of Coordination Complexes” (HTML or PDF)
Instructions: Please read this entire page and then attempt the problems. You can download a PDF version by clicking “Make PDF” at the top of the page.
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See a broken link? Please let us know!
- Lecture: iTunesU: Ontario Local Schools: “Naming Inorganic Compounds”
Link: iTunesU: Ontario Local Schools: “Naming Inorganic Compounds” (iTunes Video)
Instructions: You might be asked to launch iTunes. Please watch this entire video (approximately 53 minutes) for information on how to name simple inorganic compounds.
Terms of Use: Please respect the copyright and terms of use displayed on the webpage above.See a broken link? Please let us know!
- Reading: Boise State University: Dr. Richard Banks: “Nomenclature Tutorial for Concepts of Chemistry”
Link: Boise State University: Dr. Richard Banks: “Nomenclature Tutorial for Concepts of Chemistry” (HTML)
Instructions: Please read this entire webpage for tips on drawing naming inorganic complexes.
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- Reading: Boise State University: Dr. Richard Banks: “Naming Inorganic Compounds”
Link: Boise State University: Dr. Richard Banks: “Naming Inorganic Compounds” (HTML)
Instructions: Please read this entire webpage for tips on drawing naming inorganic complexes. Additional anion and cation examples are provided.
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- Reading: UC Davis: ChemWiki: “Nomenclature of Coordination Complexes”
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2.6 Theories of Bonding
- Reading: UC Davis: ChemWiki: “Metals, Tetrahedral and Octahedral”
Link: UC Davis: ChemWiki: “Metals, Tetrahedral and Octahedral” (HTML or PDF)
Instructions: Please read this entire webpage to gain an understanding of molecular orbital theory. You can download a PDF version by clicking “Make PDF” at the top of the page.
Terms of Use: Please respect the copyright and terms of use displayed on the webpage above.See a broken link? Please let us know!
- Reading: Imperial College: Dr. Wyn Locke: “An Introduction to Molecular Orbital Theory”
Link: Imperial College: Dr. Wyn Locke: "An Introduction to Molecular Orbital Theory” (HTML)
Instructions: Please read this entire webpage. Also, please click the links listed in the “Orbitals for Selected Molecules” section for more examples.
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- Reading: UC Davis: ChemWiki: “Molecular Orbital Theory”
Link: UC Davis: ChemWiki: “Molecular Orbital Theory” (HTML or PDF)
Instructions: Please read this entire webpage to gain an understanding molecular orbital theory. You can download a PDF version by clicking “Make PDF” at the top of the page.
Terms of Use: Please respect the copyright and terms of use displayed on the webpage above.See a broken link? Please let us know!
- Reading: Wikibooks: “Molecular Orbital Diagram”
Link: Wikibooks: “Molecular Orbital Diagram” (PDF)
Instructions: Please read this entire webpage to learn about molecular orbital diagrams.
Terms of Use: The article above is released under a Creative Commons Attribution-Share-Alike License 3.0 (HTML). You can find the original Wikibooks version of this article here (HTML).
See a broken link? Please let us know!
- Lecture: Academic Earth: MIT OpenCourseWare: Dr. Christopher Cummins: “Molecular Orbital Theory”
Link: Academic Earth: MIT OpenCourseWare: Dr. Christopher Cummins: “Molecular Orbital Theory” (Adobe Flash)
Also available in:
iTunes or mp4
Instructions: Please watch this entire video (approximately 49 minutes) for a general understanding of molecular orbital theory and how it differs from valence bond theory.
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- Lecture: Academic Earth: MIT OpenCourseWare: Dr. Christopher Cummins: “Molecular Orbital Theory for Diatomic Molecules”
Link: Academic Earth: MIT OpenCourseWare: Dr. Christopher Cummins: “Molecular Orbital Theory for Diatomic Molecules” (Adobe Flash)
Also available in:
iTunes or mp4
Instructions: Please watch this entire video (approximately 52 minutes) for a greater understanding of molecular orbital theory with regard to diatomic molecules.
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- Reading: UC Davis: ChemWiki: “Metals, Tetrahedral and Octahedral”
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2.7 Crystal/Ligand Field Theory
- Reading: UC Davis: ChemWiki: “Crystal Field Theory”
Link: UC Davis: Chemwiki: “Crystal Field Theory” (HTML or PDF)
Instructions: Please read this entire page and then attempt the problems. Be sure to watch the embedded video and also click the links offered before it. You can download a PDF version by clicking “Make PDF” at the top of the page.
Terms of Use: Please respect the copyright and terms of use displayed on the webpage above.See a broken link? Please let us know!
- Reading: University of the West Indies: Dr. Robert Lancashire: “Ligand Field Theory”
Link: University of the West Indies: Dr. Robert Lancashire: “Ligand Field Theory” (HTML)
Instructions: Please read this entire webpage and also use your mouse to change the orientation of the d-orbital lobes.
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- Reading: UC Davis: ChemWiki: “High Spin and Low Spin”
Link: UC Davis: ChemWiki: “High Spin and Low Spin” (HTML or PDF)
Instructions: Please read this entire webpage and then attempt the problems. You can download a PDF version by clicking “Make PDF” at the top of the page.
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- Reading: UC Davis: ChemWiki: “Spectrochemical Series”
Link: UC Davis: ChemWiki: “Spectrochemical Series” (HTML or PDF)
Instructions: Please read this entire webpage for a list of weak- and strong-field ligands. This material also covers subunit 7.7.2 (the halogens are considered weak-field ligands). You can download a PDF version by clicking “Make PDF” at the top of the page.
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- Reading: UC Davis: ChemWiki: “Crystal Field Theory”
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Unit 3: Bonding in Crystal Solids
Molecules that consist of charged ions with opposite charges are called “ionic.” These ionic compounds are generally solids with high melting points whose solutions conduct electrical current. Ionic compounds are generally formed from metals and nonmetal elements. The strength of chemical bonds you have encountered so far—mostly in organic chemistry—can be easily estimated by taking a look at the atoms involved. For example, an isolated C=C has a bond energy of 614 KJ/mol. In crystal solids, the strength of the ionic bonds is much more complex to evaluate than in organic molecules because many parameters, such as the charge, the size of its ions, and the geometry of the crystal need to be taken into consideration. This ionic bond energy is known as “lattice energy.” You will learn how to calculate the lattice energy in this unit.
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Learning Outcomes show close
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3.1 Crystal Systems
- Reading: Purdue University: Dr. George M. Bodner: “Unit Cells”
Link: Purdue University: Dr. George M. Bodner: “Unit Cells” (HTML)
Instructions: Please read this entire webpage to gain an understanding of unit cells and the types of inorganic crystal structures. Also, please attempt the Face Centered-Cubic Structure Learning Activity. This material also covers subunits 3.1, 4.1, and 4.3.
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- Reading: Purdue University: Dr. George M. Bodner: “Unit Cells”
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3.2 Solid State Structures of Crystal Lattices
- Reading: NDT Resource Center: “Solid State Structure”
Link: NDT Resource Center: “Solid State Structure” (HTML)
Instructions: Please read this entire webpage to gain an understanding of types of inorganic solids.
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- Reading: Friends School Chemistry: Ken Drews: “Solid State Structures”
Link: Friends School Chemistry: Ken Drews: “Solid State Structures” (HTML)
Instructions: Please read this entire webpage to gain an understanding of the types of inorganic solids, bonds, and intermolecular forces.
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- Reading: NDT Resource Center: “Solid State Structure”
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3.3 Atomic Size Revisited—Ionic Radii and Real Crystals
- Reading: Wikipedia: “Ionic Radius”
Link: Wikipedia: “Ionic Radius” (PDF)
Instructions: Please read this entire webpage to gain an understanding of ionic radii with regard to crystal lattices.
Terms of Use: The article above is released under a Creative Commons Attribution-Share-Alike License 3.0 (HTML). You can find the original Wikipedia version of this article here (HTML).See a broken link? Please let us know!
- Reading: Wikipedia: “Ionic Radius”
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3.4 Lattice Energy and the Born-Haber Cycle
- Reading: University of Waterloo: Dr. Peter Chieh: “Lattice Energy”
Link: University of Waterloo: Dr. Peter Chieh: “Lattice Energy” (HTML)
Instructions: Please read this entire page and then attempt the problems.
Terms of Use: Please respect the copyright and terms of use displayed on the webpage above.See a broken link? Please let us know!
- Reading: Penn State University, Erie: Dr. Alan J. Jircitano: “Electrons in Molecules”
Link: Penn State University, Erie: Dr. Alan J. Jircitano: “Electrons in Molecules” (HTML)
Instructions: Please read this entire page for a Born-Haber cycle example using sodium chloride.
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- Reading: University of Waterloo: Dr. Peter Chieh: “Lattice Energy”
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Unit 4: Ionic Solids
Ionic solids take on specific three-dimensional structures based on the size of the atoms. In this unit, we will see the similarities and differences between these structures. We will first look at the unit cell and then transition into more complex packing patterns.
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Learning Outcomes show close
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4.1 The Packing of Spheres and the Unit Cell
- Reading: University of Massachusetts, Lowell: Dr. Nancy De Luca: “Crystalline Solids”
Link: University of Massachusetts, Lowell: Dr. Nancy De Luca: “Crystalline Solids” (HTML and PowerPoint)
Instructions: Please scroll down the page until you reach October 19 & 21 under Class Date. Under the Topics heading, click the links for the Crystalline Solids text and PowerPoint presentation. Please read these entire documents to gain an overview of crystals and ionic solids. These materials also cover subunits 4.1 through 4.4.
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Note: Unit cells are the basis of discussion of ionic solids. They are the smallest repeating unit structure within a solid.See a broken link? Please let us know!
- Reading: University of Massachusetts, Lowell: Dr. Nancy De Luca: “Crystalline Solids”
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4.1.1 Cubic Close Packing
- Reading: Louisiana State University: Dr. Steven F. Watkins: “Cubic Closest Packing”
Link: Louisiana State University: Dr. Steven F. Watkins: “Cubic Closest Packing” (HTML)
Instructions: Please read this entire webpage to gain an understanding of cubic close packing.
Terms of Use: The material above has been reposted with permission by Steven Watkins. Please respect the copyright and terms of use displayed on the webpage above.See a broken link? Please let us know!
- Reading: Louisiana State University: Dr. Steven F. Watkins: “Coordination in CCP”
Link: Louisiana State University: Dr. Steven F. Watkins: “Coordination in CCP” (HTML)
Instructions: Please read this entire webpage to gain an understanding of cubic close packing.
Terms of Use: The material above has been reposted with permission by Steven Watkins. Please respect the copyright and terms of use displayed on the webpage above.See a broken link? Please let us know!
- Reading: Louisiana State University: Dr. Steven F. Watkins: “Cubic Closest Packing”
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4.1.2 Hexagonal Close Packing
- Reading: Louisiana State University: Dr. Steven F. Watkins: “Hexagonal Closest Packing”
Link: Louisiana State University: Dr. Steven F. Watkins: “Hexagonal Closest Packing” (HTML)
Instructions: Please read this entire webpage to gain an understanding of hexagonal close packing.
Terms of Use: The material above has been reposted with permission by Steven Watkins. Please respect the copyright and terms of use displayed on the webpage above.See a broken link? Please let us know!
- Reading: Louisiana State University: Dr. Steven F. Watkins: “Coordination in HCP”
Link: Louisiana State University: Dr. Steven F. Watkins: “Coordination in HCP” (HTML)
Instructions: Please read this entire webpage to gain an understanding of hexagonal close packing.
Terms of Use: The material above has been reposted with permission by Steven Watkins. Please respect the copyright and terms of use displayed on the webpage above.See a broken link? Please let us know!
- Reading: Oxford University: Dr. S. J. Heyes: “Close-Packing of Spheres”
Link: Oxford University: Dr. S. J. Heyes: “Close-Packing of Spheres” (HTML)
Instructions: Please read this entire section. This material provides graphical representations of cubic and hexagonal close packing.
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- Reading: Louisiana State University: Dr. Steven F. Watkins: “Hexagonal Closest Packing”
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4.1.3 Interstitial Holes
- Reading: Louisiana State University: Dr. Steven F. Watkins: “Tetrahedral Interstices”
Link: Louisiana State University: Dr. Steven F. Watkins: “Tetrahedral Interstices” (HTML)
Instructions: Please read this entire webpage to gain an understanding of tetrahedral holes.
Terms of Use: The material above has been reposted with permission by Steven Watkins. Please respect the copyright and terms of use displayed on the webpage above.See a broken link? Please let us know!
- Reading: Louisiana State University: Dr. Steven F. Watkins: “Octahedral Interstices”
Link: Louisiana State University: Dr. Steven F. Watkins: “Octahedral Interstices” (HTML)
Instructions: Please read this entire webpage to gain an understanding of octahedral holes.
Terms of Use: The material above has been reposted with permission by Steven Watkins. Please respect the copyright and terms of use displayed on the webpage above.See a broken link? Please let us know!
- Reading: Oxford University: Dr. S. J. Heyes: “Location of Interstitial Holes in Close-Packed Structures”
Link: Oxford University: Dr. S. J. Heyes: “Location of Interstitial Holes in Close-Packed Structures” (HTML)
Instructions: Please read this entire section. This material provides graphical representations of tetrahedral and octahedral holes.
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- Reading: Louisiana State University: Dr. Steven F. Watkins: “Tetrahedral Interstices”
- 4.2 Noncubic Close Packing
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4.2.1 Simple Cubic
- Reading: Louisiana State University: Dr. Steven F. Watkins: “Simple Cubic”
Link: Louisiana State University: Steven F. Watkins: “Simple Cubic” (HTML)
Instructions: Please read this entire webpage to gain an understanding of simple cubic crystal lattice systems.
Terms of Use: The material above has been reposted with permission by Steven Watkins. Please respect the copyright and terms of use displayed on the webpage above.See a broken link? Please let us know!
- Reading: Louisiana State University: Dr. Steven F. Watkins: “Simple Cubic”
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4.2.2 Body-Centered Cubic
- Reading: Louisiana State University: Dr. Steven F. Watkins: “Body Centered Cubic”
Link: Louisiana State University: Dr. Steven F. Watkins: “Body Centered Cubic” (HTML)
Instructions: Please read this entire webpage to gain an understanding of body-centered crystal lattice systems.
Terms of Use: The material above has been reposted with permission by Steven Watkins. Please respect the copyright and terms of use displayed on the webpage above.See a broken link? Please let us know!
- Reading: Louisiana State University: Dr. Steven F. Watkins: “Body Centered Cubic”
- 4.3 Metallic Radii
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4.4 Packing of Alloys
Note: Alloys are structures containing more than one metal, such as brass (composed of copper and zinc), or a metal with certain nonmetals, such as steel (composed of iron and carbon).
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Unit 5: Solid State Chemistry
Solid state chemistry studies the behavior of a very large aggregation of atoms that form crystals and solid networks. Recall from molecular orbital theory that electrons in a molecule populate distinct orbitals located at distinct energy levels. Electrons populate the low-energy orbitals first. These electrons can be excited into high-energy orbitals by heat or absorption of light. In large aggregations of atoms, such as in a solid network, low-energy orbitals are so close (in terms of energy levels) and numerous that they form a continuous band of orbitals. Electrons can easily move from one orbital to another within this band. In solid networks, the majority of the electrons populate a single band (known as the valence band), which is the equivalent of all the low-energy orbitals of molecules. As electrons in single molecules can be excited into higher-energy orbitals, electrons in the valence band can be excited into the high energy band (called the conductive band). The difference in energy between the valence and conductive band is called “band gap energy”; different materials can have very different band gap energies. You must understand how the band gap is formed and how electrons can move from one band to another in order to comprehend such properties as electrical conductivity and heat conduction in materials.
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5.1 Band Theory
- Lecture: Academic Earth: MIT OpenCourseWare: Dr. Donald R. Sadoway: “Metallic Bonding, Band Theory, Band Gaps”
Link: Academic Earth: MIT OpenCourseWare: Dr. Donald R. Sadoway: “Metallic Bonding, Band Theory, Band Gaps” (Adobe Flash)
Also available in:
iTunes or mp4
Instructions: Please watch this entire video (approximately 50 minutes) for a greater understanding of band theory.
Terms of Use: Please respect the copyright and terms of use displayed on the webpage above.See a broken link? Please let us know!
- Reading: University of Adelaide: “Solid-State Band Theory”
Link: University of Adelaide: “Solid-State Band Theory” (HTML)
Instructions: Please read this entire webpage for a brief discussion on band theory.
Terms of Use: Please respect the copyright and terms of use displayed on the webpage above.See a broken link? Please let us know!
- Reading: UC Davis: ChemWiki: “Band Theory of Metals and Insulators”
Link: UC Davis: ChemWiki: “Band Theory of Metals and Insulators” (HTML or PDF)
Instructions: Please read this entire webpage and then attempt the problems. This material also covers subunit 5.3. You can download a PDF version by clicking “Make PDF” at the top of the page.
Terms of Use: Please respect the copyright and terms of use displayed on the webpage above.See a broken link? Please let us know!
- Reading: Georgia State University: “Band Theory of Solids”
Link: Georgia State University: “Band Theory of Solids” (HTML)
Instructions: Please read this entire webpage for a slightly different approach to band theory. Also, please click both semiconductor links. This material also covers subunits 5.3 and 5.4.
Terms of Use: Please respect the copyright and terms of use displayed on the webpage above.See a broken link? Please let us know!
- Lecture: Academic Earth: MIT OpenCourseWare: Dr. Donald R. Sadoway: “Metallic Bonding, Band Theory, Band Gaps”
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5.2 Metals and Alloys
- Reading: The Pennsylvania State University: “Metals and Alloys”
Link: The Pennsylvania State University: “Metals and Alloys” (HTML)
Instructions: Please read this entire webpage for detailed information of the structures and bonding properties of metals and alloys. The topics of coordination and conductivity are also discussed.
Terms of Use: Please respect the copyright and terms of use displayed on the webpage above.See a broken link? Please let us know!
- Reading: The Pennsylvania State University: “Metals and Alloys”
- 5.3 Insulators
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5.4 Semiconductors
- Reading: UC Davis: ChemWiki: “Band Theory of Semiconductors”
Link: UC Davis: ChemWiki: “Band Theory of Semiconductors” (HTML or PDF)
Instructions: Please read this entire webpage and then attempt the problems. You can also view this material in PDF. You can download a PDF version by clicking “Make PDF” at the top of the page.
Terms of Use: Please respect the copyright and terms of use displayed on the webpage above.See a broken link? Please let us know!
- Reading: UC Davis: ChemWiki: “Band Theory of Semiconductors”
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5.5 Intrinsic and Extrinsic
- Reading: UC Davis: ChemWiki: “Intrinsic Semiconductors”
Link: UC Davis: ChemWiki: “Intrinsic Semiconductors” (HTML or PDF)
Instructions: Please read this entire webpage and then attempt the problems. You can download a PDF version by clicking “Make PDF” at the top of the page.
Terms of Use: Please respect the copyright and terms of use displayed on the webpage above.See a broken link? Please let us know!
- Reading: UC Davis: ChemWiki: “Extrinsic Semiconductors”
Link: UC Davis: ChemWiki: “Extrinsic Semiconductors” (HTML or PDF)
Instructions: Please read this entire webpage and then attempt the problems. You can download a PDF version by clicking “Make PDF” at the top of the page.
Terms of Use: Please respect the copyright and terms of use displayed on the webpage above.See a broken link? Please let us know!
- Reading: UC Davis: ChemWiki: “Intrinsic Semiconductors”
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5.6 p-Type and n-Type
- Reading: Wikipedia: “P-Type Semiconductor”
Link: Wikipedia: “P-Type Semiconductor” (PDF)
Instructions: Please read this entire webpage for information on doping and p-type superconductors.
Terms of Use: The article above is released under a Creative Commons Attribution-Share-Alike License 3.0 (HTML). You can find the original Wikipedia version of this article here (HTML).See a broken link? Please let us know!
- Reading: Wikipedia: “N-Type Semiconductor”
Link: Wikipedia: “N-Type Semiconductor” (PDF)
Instructions: Please read this entire webpage for information on the nature n-type semiconductors.
Terms of Use: The article above is released under a Creative Commons Attribution-Share-Alike License 3.0 (HTML). You can find the original Wikipedia version of this article here (HTML).See a broken link? Please let us know!
- Reading: Wikipedia: “P-Type Semiconductor”
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5.7 Superconductors
- Reading: Chemistry Explained: “Superconductors”
Link: Chemistry Explained: “Superconductors” (HTML)
Instructions: Please read this entire webpage for an overview of semiconductors. This material also covers subunit 5.7.2.
Terms of Use: Please respect the copyright and terms of use displayed on the webpage above.See a broken link? Please let us know!
- Reading: Chemistry Explained: “Superconductors”
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5.7.1 Low Temperature
- Reading: University of Bristol: Ben Truscott: “What Is Low-Temperature Superconductivity?”
Link: University of Bristol: Ben Truscott: “What Is Low-Temperature Superconductivity?” (HTML)
Instructions: Please read this entire webpage for information on the nature of superconductivity.
Terms of Use: Please respect the copyright and terms of use displayed on the webpage above.See a broken link? Please let us know!
- Reading: University of Bristol: Ben Truscott: “Which Elements Are Low-Temperature Superconductors?”
Link: University of Bristol: Ben Truscott: “Which Elements Are Low-Temperature Superconductors?” (HTML)
Instructions: Please read this entire webpage for examples of elemental superconductors.
Terms of Use: Please respect the copyright and terms of use displayed on the webpage above.See a broken link? Please let us know!
- Reading: University of Bristol: Ben Truscott: “What Is Low-Temperature Superconductivity?”
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5.7.2 High Temperature
- Reading: Wikipedia: “High-Temperature Superconductivity”
Link: Wikipedia: “High-Temperature Superconductivity” (PDF)
Instructions: Please read this entire webpage for information on the nature of high-temperature superconductivity and for examples of high-temperature superconductors.
Terms of Use: The article above is released under a Creative Commons Attribution-Share-Alike License 3.0 (HTML). You can find the original Wikipedia version of this article here (HTML).See a broken link? Please let us know!
- Reading: Wikipedia: “High-Temperature Superconductivity”
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Unit 6: Acids and Bases
In this unit, we will study the acids and bases of inorganic metals and nonmetals. The concept of an acid as an electron acceptor and a base as an electron donor would greatly expand the number of compounds considered acidic or basic. We will also review classical acids and bases, such as the Brønsted-Lowry definition of acids and bases. We will in turn study the Lewis concept of acids and bases and introduce a new approach to understanding acidity and basicity, whereby acids and bases are defined as “hard” and “soft” (the hard/soft acid/base [HSAB] theory) based on their size, charge density, and polarizability. We will also discuss the use of activity as a measure for the concentration of a solution, the acids of metal oxoacids (e.g., chromic acid), and the amphoteric behavior of certain chemical compounds (compounds that can be acids and bases).
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6.1 Molarity, Molality, and Standard State
- Reading: Wikipedia: “Molar Concentration,” “Molality,” and “Standard State”
Links: Wikipedia: “Molar Concentration” (PDF), “Molality” (PDF), and “Standard State” (PDF)
Instructions: Please read these entire webpages for an overview of molarity, molality, and the standard state reference point.
Terms of Use: Please respect the copyright and terms of use displayed on the webpages above.See a broken link? Please let us know!
- Reading: Wikipedia: “Molar Concentration,” “Molality,” and “Standard State”
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6.2 Activity
Note: The activity of a solution takes into account the interactions between solute particles in very concentrated solutions
- Reading: Wikipedia: “Activity (chemistry)”
Link: Wikipedia: “Activity (chemistry)” (PDF)
Instructions: Please read this entire webpage for an overview of effective concentrations and ideal solutions.
Terms of Use: Please respect the copyright and terms of use displayed on the webpage above.See a broken link? Please let us know!
- Reading: Wikipedia: “Activity (chemistry)”
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6.3 Brønsted-Lowry Acids and Bases
- Reading: The Basics of General, Organic, and Biological Chemistry: “Chapter 10, Section 2: Brønsted-Lowry Definition of Acids and Bases”
Link: The Basics of General, Organic, and Biological Chemistry: “Chapter 10, Section 2: Brønsted-Lowry Definition of Acids and Bases” (PDF)
Instructions: Read this section and then attempt the exercises at the end of the chapter.
Terms of Use: This text was adapted by The Saylor Foundation under a Creative Commons Attribution-NonCommercial-ShareAlike 3.0 License without attribution as requested by the work’s original creator or licensee.See a broken link? Please let us know!
- Lecture: Academic Earth: MIT OpenCourseWare: Dr. Christopher Cummins: “Lewis and Bronsted Acid-Base Concepts”
Link: Academic Earth: MIT OpenCourseWare: Dr. Christopher Cummins: “Lewis and Bronsted Acid-Base Concepts” (Adobe Flash)
Also available in:
iTunes or mp4
Instructions: Please watch this entire video (approximately 43 minutes) for a greater understanding of Lewis and Brønsted acids and bases. This video also covers subunits 6.3 and 6.4.
Terms of Use: Please respect the copyright and terms of use displayed on the webpage above.See a broken link? Please let us know!
- Reading: The Basics of General, Organic, and Biological Chemistry: “Chapter 10, Section 2: Brønsted-Lowry Definition of Acids and Bases”
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6.4 Lewis Acids and Bases
- Reading: The Basics of General, Organic, and Biological Chemistry: “Chapter 10, Section 1: Arrhenius Definition of Acids and Bases”
Link: The Basics of General, Organic, and Biological Chemistry: “Chapter 10, Section 1: Arrhenius Definition of Acids and Bases” (PDF)
Instructions: Read this section and then attempt the exercises at the end of the chapter.
Terms of Use: This text was adapted by The Saylor Foundation under a Creative Commons Attribution-NonCommercial-ShareAlike 3.0 License without attribution as requested by the work’s original creator or licensee.See a broken link? Please let us know!
- Reading: UC Davis: Chemwiki: “Lewis Concept of Acids and Bases”
Link: UC Davis: Chemwiki: “Lewis Concept of Acids and Bases” (HTML or PDF)
Instructions: Please read this entire webpage and then attempt the problems. You can download a PDF version by clicking “Make PDF” at the top of the page.
Terms of Use: Please respect the copyright and terms of use displayed on the webpage above.See a broken link? Please let us know!
- Reading: The Basics of General, Organic, and Biological Chemistry: “Chapter 10, Section 1: Arrhenius Definition of Acids and Bases”
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6.5 Hard/Soft Acids and Bases
- Reading: University of Massachusetts, Lowell: Dr. Nancy De Luca: “Acids & Bases”
Link: University of Massachusetts, Lowell: Dr. Nancy De Luca: “Acids & Bases” (PowerPoint)
Instructions: Please scroll down the page until you reach October 7 & 14 under Class Date. Under the Topics heading, click the link for the Acids & Bases PowerPoint presentation. Please read this entire presentation to gain an overview of the hard/soft acid/base theory.
Terms of Use: Please respect the copyright and terms of use displayed on the webpage above.See a broken link? Please let us know!
- Reading: University of Massachusetts, Lowell: Dr. Nancy De Luca: “Acids & Bases”
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6.6 Inorganic Acids
- Reading: Washington University of St. Louis: “Inorganic Acids”
Link: Washington University of St. Louis: “Inorganic Acids” (HTML)
Instructions: Please read this entire webpage for a listing of inorganic acids halides.
Terms of Use: Please respect the copyright and terms of use displayed on the webpage above.The Saylor Foundation does not yet have materials for this portion of the course. If you are interested in contributing your content to fill this gap or aware of a resource that could be used here, please submit it here.
- Reading: Washington University of St. Louis: “Inorganic Acids”
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6.6.1 Hydrogen Halides
- Reading: Chemguide: “The Acidity of the Hydrogen Halides”
Link: Chemguide: “The Acidity of the Hydrogen Halides” (HTML)
Instructions: Please read this entire webpage for information on the synthesis and properties of hydrogen halides. This material also covers subunits 6.8 (for hydrogen halides).
Terms of Use: Please respect the copyright and terms of use displayed on the webpage above.See a broken link? Please let us know!
- Reading: Chemguide: “The Acidity of the Hydrogen Halides”
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6.6.2 Oxoacids
- Reading: Wikipedia: “Oxoacid”
Link: Wikipedia: “Oxoacid” (PDF)
Instructions: Please read this entire webpage to gain an understanding of oxoacids. This material also covers subunits 7.1.2, 7.2.3, 7.3.5, 7.5.2, 7.6.3, and 7.7.3.
Terms of Use: The article above is released under a Creative Commons Attribution-Share-Alike License 3.0 (HTML). You can find the original Wikipedia version of this article here (HTML).
See a broken link? Please let us know!
- Reading: Wikipedia: “Oxoacid”
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6.7 Inorganic Bases
- Reading: Oklahoma State University: Laboratory Safety Manual: “Inorganic Bases”
Link: Oklahoma State University: Laboratory Safety Manual: “Inorganic Bases” (HTML)
Instructions: Please read this entire section for a listing of common inorganic acids. Please see subunits 7.1 through 7.3 for greater detail on these compounds.
Terms of Use: Please respect the copyright and terms of use displayed on the webpage above.See a broken link? Please let us know!
- Reading: Oklahoma State University: Laboratory Safety Manual: “Inorganic Bases”
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6.8 Enthalpy of Dissociation of Acids
- Reading: Purdue University: George M. Bodner's “The Relationship Between Free Energy and Equilibrium Constants”
Link: Purdue University: George M. Bodner's “The Relationship Between Free Energy and Equilibrium Constants”
Instructions: Please read through the entire section and work through practice problems 9 & 10. For question 9, ΔG from problem 7 is -32.96 kJ. Question 10 deals specifically with acid dissociation constants and Gibbs free energy. Please remember that gibbs free energy is related to enthalpy via the following equation: ΔG = ΔH – TΔS. A review of this concept is found in a preceding section of the webpage listed.
Terms of Use: Please respect the copyright and terms of use displayed on the webpage above.See a broken link? Please let us know!
- Reading: Jim Clark's Chemguide: “The Acidity of Hydrogen Halides”
Link: Jim Clark's Chemguide: “The Acidity of Hydrogen Halides”
Instructions: Please read through the entire webpage. This material uses a thermodynamic approach to explain the relative acidity of the hydrogen halide series and explains why HF is a weak acid.
Terms of Use: Please respect the copyright and terms of use displayed on the webpage above.See a broken link? Please let us know!
- Web Media: Davidson College: David N. Blauch’s “Virtual Chemistry Experiments: Heat of Solution of Sulfuric Acid”
Link: Davidson College: David N. Blauch's “Virtual Chemistry Experiments: Heat of Solution of Sulfuric Acid”
Instructions: Please follow the specific instructions on the page in order to complete this experiment. This experiment will help you visualize the release of enthalpy upon dissociation of acid in water. Be aware that acid dissociation is often referred to as heat of solution. If you need assistance calculating qrxn for the system, an explanation is given in “heat of solution of ammonium nitrate” experiment (link provided on page).
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- Reading: Purdue University: George M. Bodner's “The Relationship Between Free Energy and Equilibrium Constants”
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6.9 Periodic Trends in Amphoteric Structures
- Reading: Western Oregon University: “Periodic Trends and Oxides”
Link: Western Oregon University: “Periodic Trends and Oxides” (HTML)
Instructions: Please scroll down to “Amphoteric Oxides” and then read this entire section for information on the inorganic acid electronegativity trend.
Terms of Use: Please respect the copyright and terms of use displayed on the webpage above.
Note: Amphoteric structures are able to act as acids and bases.See a broken link? Please let us know!
- Reading: Western Oregon University: “Periodic Trends and Oxides”
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Unit 7: Groups 1–7 of the Periodic Table
In this unit, we will look at the properties of the elements in Groups 1–7 of the periodic table. We will also discuss organometallic compounds of the elements within each respective group. Remember that organometallics is the study of metals bonded to nonmetals. In organic chemistry, we have seen organometallic reagents in the form of Grignard reagents, metal hydrides, etc.
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Learning Outcomes show close
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7.1 Group 1: Alkali Metals
- Reading: UC Davis: ChemWiki: “Group 1: The Alkali Metals”
Link: UC Davis: ChemWiki: “Group 1: The Alkali Metals” (HTML or PDF)
Instructions: Please read this entire webpage and then attempt the problems. Please be sure to view the Google Videos linked on this webpage. This material also covers subunits 7.1.1 and 7.1.2. You can download a PDF version by clicking “Make PDF” at the top of the page.
Terms of Use: Please respect the copyright and terms of use displayed on the webpage above.See a broken link? Please let us know!
- Reading: WebElements: “Lithium,” “Sodium,” “Potassium,” “Rubidium,” “Caesium,” and “Francium”
Links: WebElements: “Lithium,” “Sodium,” “Potassium,” “Rubidium,” “Caesium,” and “Francium” (HTML)
Note: All the resources above are in HTML format.
Instructions: Please read these entire webpages. Look on the left-hand side of the page for the “Chemistry and Compounds” heading. In the links under this section, you will find detailed examples of complexes and reactions for each Group 1 metal. These materials also cover subunits 7.1.1 through 7.1.3.
Terms of Use: Please respect the copyright and terms of use displayed on the webpages above.See a broken link? Please let us know!
- Reading: UC Davis: ChemWiki: “Group 1: The Alkali Metals”
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7.1.1 Reactivity
- Reading: Chemguide: “Reactions of the Group 1 Elements with Water” and “Reactions of the Group 2 Elements with Oxygen and Chlorine”
Links: Chemguide: “Reactions of the Group 1 Elements with Water” (HTML) and “Reactions of the Group 2 Elements with Oxygen and Chlorine” (HTML)
Instructions: Please read these entire webpages for detailed information on Group 1 metal reactions.
Terms of Use: Please respect the copyright and terms of use displayed on the webpages above.See a broken link? Please let us know!
- Reading: Chemguide: “Reactions of the Group 1 Elements with Water” and “Reactions of the Group 2 Elements with Oxygen and Chlorine”
- 7.1.2 Formation of Hydroxides, Oxides, and Salts with Oxoacids
- 7.1.3 Hydration of Cations
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7.1.4 Deprotonation of Organic Molecules by Alkali Metals
- Reading: Wikipedia: “Organolithium Reagent”
Link: Wikipedia: “Organolithium Reagent” (PDF)
Instructions: Please read this entire webpage to gain an understanding of synthesis, structure, and properties of organolithium compounds. This material also covers subunit 7.1.5.
Terms of Use: The article above is released under a Creative Commons Attribution-Share-Alike License 3.0 (HTML). You can find the original Wikipedia version of this article here (HTML).See a broken link? Please let us know!
- Reading: Wikipedia: “Organosodium Chemistry”
Link: Wikipedia: “Organosodium Chemistry” (PDF)
Instructions: Please read this entire webpage to gain an understanding of synthesis, structure, and properties of organosodium compounds. The section “Higher Alkali Metals” provides information on organopotassium, organorubidium, and organocaesium complexes.
Terms of Use: The article above is released under a Creative Commons Attribution-Share-Alike License 3.0 (HTML). You can find the original Wikipedia version of this article here (HTML).
See a broken link? Please let us know!
- Reading: Wikipedia: “Organolithium Reagent”
- 7.1.5 Basicity of Organolithium Compounds
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7.2 Group 2: Alkaline Earth Metals
- Reading: UC Davis: ChemWiki: “Group 2: The Alkaline Earth Metals”
Link: UC Davis: ChemWiki: “Group 2: The Alkaline Earth Metals” (HTML or PDF)
Instructions: Please read this entire webpage and then attempt the problems. This material also covers subunits 7.2.1 through 7.2.4. You can download a PDF version by clicking “Make PDF” at the top of the page.
Terms of Use: Please respect the copyright and terms of use displayed on the webpage aboveSee a broken link? Please let us know!
- Reading: WebElements: “Beryllium,” “Magnesium,” “Calcium,” “Strontium,” “Barium,” and “Radium”
Links: WebElements: “Beryllium,” “Magnesium,” “Calcium,” “Strontium,” “Barium,” and “Radium” (HTML)
Note: All the resources above are in HTML format.
Instructions: Please read these entire webpages. Look on the left-hand side of the page for the “Chemistry and Compounds” heading. In the links under this section, you will find detailed examples of complexes and reactions for each Group 2 metal. These materials also cover subunits 7.2.1 through 7.2.4.
Terms of Use: Please respect the copyright and terms of use displayed on the webpages above.See a broken link? Please let us know!
- Reading: UC Davis: ChemWiki: “Group 2: The Alkaline Earth Metals”
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7.2.1 Reactivity
- Reading: Chemguide: “Reactions of the Group 2 Elements with Water” and “Reactions of the Group 2 Elements with Air or Oxygen”
Links: Chemguide: “Reactions of the Group 2 Elements with Water” (HTML) and “Reactions of the Group 2 Elements with Air or Oxygen” (HTML)
Instructions: Please read these entire webpages for detailed information on Group 2 metal reactions.
Terms of Use: Please respect the copyright and terms of use displayed on the webpages above.See a broken link? Please let us know!
- Reading: Chemguide: “Reactions of the Group 2 Elements with Water” and “Reactions of the Group 2 Elements with Air or Oxygen”
- 7.2.2 Salts Formed with Halides
- 7.2.3 Salts Formed with Oxides, Hydroxides, and Oxoacids
- 7.2.4 Hydration of Group 2 Elements
- 7.2.5 Ligands of Group 2 Elements
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7.2.6 Grignard Reagents
- Reading: UC Davis: ChemWiki: “Reactions of Alkyl Halides with Reducing Metals”
Link: UC Davis: ChemWiki: “Reactions of Alkyl Halides with Reducing Metals” (HTML or PDF)
Instructions: Please read this entire webpage for information on Grignard reagents. You can download a PDF version by clicking “Make PDF” at the top of the page.
Terms of Use: Please respect the copyright and terms of use displayed on the webpage above.See a broken link? Please let us know!
- Reading: UC Davis: ChemWiki: “Reactions of Alkyl Halides with Reducing Metals”
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7.3 Group 3 Elements
- Reading: UC Davis: ChemWiki: “Group 13: The Boron Family”
Link: UC Davis: ChemWiki: “Group 13: The Boron Family” (HTML or PDF)
Instructions: Please read this entire webpage and then attempt the problems. This material also covers subunits 7.3.1 and 7.3.2. You can download a PDF version by clicking “Make PDF” at the top of the page.
Terms of Use: Please respect the copyright and terms of use displayed on the webpage above.See a broken link? Please let us know!
- Reading: WebElements: “Boron,” “Aluminum,” “Gallium,” “Indium,” and “Thallium”
Links: WebElements: “Boron,” “Aluminum,” “Gallium,” “Indium,” and “Thallium” (HTML)
Note: All the resources above are in HTML format.
Instructions: Please read these entire webpages. Look on the left-hand side of the page for the “Chemistry and Compounds” heading. In the links under this section, you will find detailed examples of complexes, reactions, reduction potentials, and oxidation states for each boron group metal. These materials also cover subunits 7.3.2 through 7.3.5.
Terms of Use: Please respect the copyright and terms of use displayed on the webpages above.See a broken link? Please let us know!
- Reading: UC Davis: ChemWiki: “Group 13: The Boron Family”
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7.3.1 Oxidation States
- Reading: Wikipedia: “List of Oxidation States of the Elements”
Link: Wikipedia: “List of Oxidation States of the Elements” (PDF)
Instructions: Please read this entire webpage, which provides a list of the common oxidation states of all the periodic table elements, including those of the boron group.
Terms of Use: The article above is released under a Creative Commons Attribution-Share-Alike License 3.0 (HTML). You can find the original Wikipedia version of this article here (HTML).See a broken link? Please let us know!
- Reading: Wikipedia: “List of Oxidation States of the Elements”
- 7.3.2 Reactivity
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7.3.3 Hydrides and Halides of Boron
Note: Recall from organic chemistry that boron-containing complexes, such as sodium borohydride, are commonly used to reduce carbonyls through hydride donation.
- 7.3.4 Halides of Other Group 3 Elements
- 7.3.5 Oxides, Oxoacids, Oxanions, and Hydroxides of Group 3 Elements
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7.4 Group 4 Elements
- Reading: UC Davis: ChemWiki: “Group 14: The Carbon Family”
Link: UC Davis: ChemWiki: “Group 14: The Carbon Family” (HTML or PDF)
Instructions: Please read this entire webpage and then attempt the problems. You can download a PDF version by clicking “Make PDF” at the top of the page.
Terms of Use: Please respect the copyright and terms of use displayed on the webpage above.See a broken link? Please let us know!
- Reading: WebElements: “Carbon,” “Silicon,” “Germanium,” “Tin,” and “Lead”
Links: WebElements: “Carbon,” “Silicon,” “Germanium,” “Tin,” and “Lead” (HTML)
Note: All the resources above are available in HTML format.
Instructions: Please read these entire webpages. Look on the left-hand side of the page for the “Chemistry and Compounds” heading. In the links under this section, you will find detailed examples of complexes, reactions, and bond enthalpies for each carbon group metal. These materials also cover subunits 7.4.1 through 7.4.3.
Terms of Use: Please respect the copyright and terms of use displayed on the webpages above.See a broken link? Please let us know!
- Reading: UC Davis: ChemWiki: “Group 14: The Carbon Family”
- 7.4.1 Bond Enthalpy
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7.4.2 Carbon and Silicon Halides
- Reading: Chemguide: “The Chlorides of Carbon, Silicon and Lead”
Link: Chemguide: “The Chlorides of Carbon, Silicon and Lead” (HTML)
Instructions: Please read this entire webpage for information on the synthesis and properties of carbon, silicon, and lead chlorides.
Terms of Use: Please respect the copyright and terms of use displayed on the webpage above.
See a broken link? Please let us know!
- Reading: Chemguide: “The Chlorides of Carbon, Silicon and Lead”
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7.4.3 Carbon and Silicon Oxides and Oxacids
- Reading: Chemguide: “The Oxides of Group 4”
Link: Chemguide: “The Oxides of Group 4” (HTML)
Instructions: Please read this entire webpage for information on the synthesis and properties of Group 4 oxides.
Terms of Use: Please respect the copyright and terms of use displayed on the webpage above.See a broken link? Please let us know!
- Reading: Chemguide: “The Oxides of Group 4”
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7.5 Group 5 Elements
- Reading: UC Davis: ChemWiki: “Group 15: The Nitrogen Family”
Link: UC Davis: ChemWiki: “Group 15: The Nitrogen Family” (HTML or PDF)
Instructions: Please read this entire webpage and then attempt the problems. You can download a PDF version by clicking “Make PDF” at the top of the page.
Terms of Use: Please respect the copyright and terms of use displayed on the webpage above.See a broken link? Please let us know!
- Reading: WebElements: “Nitrogen,” “Phosphorus,” “Arsenic,” “Antimony,” and “Bismuth”
Links: WebElements: “Nitrogen,” “Phosphorus,” “Arsenic,” “Antimony,” and “Bismuth” (HTML)
Note: All the materials above are available in HTML format.
Instructions: Please read these entire webpages. Look on the left-hand side of the page for the “Chemistry and Compounds” heading. In the links under this section, you will find detailed examples of complexes and reactions for each nitrogen group metal. These materials also cover subunits 7.5.1 through 7.5.3.
Terms of Use: Please respect the copyright and terms of use displayed on the webpages above.See a broken link? Please let us know!
- Reading: UC Davis: ChemWiki: “Group 15: The Nitrogen Family”
- 7.5.1 Trihydrides of Group 5 Elements
- 7.5.2 Halides and Oxoacids of Group of 5 Elements
- 7.5.3 Nitrogen and Oxygen Compounds
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7.6 Group 6 Elements
- Reading: UC Davis: ChemWiki: “Group 16: The Oxygen Family”
Link: UC Davis: ChemWiki: “Group 16: The Oxygen Family” (HTML or PDF)
Instructions: Please read this entire webpage and then attempt the problems. You can download a PDF version by clicking “Make PDF” at the top of the page.
Terms of Use: Please respect the copyright and terms of use displayed on the webpage above.See a broken link? Please let us know!
- Reading: WebElements: “Oxygen,” “Sulfur,” “Selenium,” “Tellurium,” and “Polonium”
Links: WebElements: “Oxygen,” “Sulfur,” “Selenium,” “Tellurium,” and “Polonium” (HTML)
Instructions: Please read these entire webpages. Look on the left-hand side of the page for the “Chemistry and Compounds” heading. In the links under this section, you will find detailed examples of complexes and reactions for each oxygen group metal. These materials also cover subunits 7.6.1 through 7.6.3.
Terms of Use: Please respect the copyright and terms of use displayed on the webpages above.See a broken link? Please let us know!
- Reading: UC Davis: ChemWiki: “Group 16: The Oxygen Family”
- 7.6.1 Compounds Formed from Oxygen and Sulfur
- 7.6.2 Compounds Formed from Halides with Oxygen and Sulfur
- 7.6.3 Oxacids of Sulfur
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7.7 Group 7 Elements: Halogens
- Reading: UC Davis: ChemWiki: “Group 17: The Halogens”
Link: UC Davis: ChemWiki: “Group 17: The Halogens” (HTML or PDF)
Instructions: Please read this entire webpage and then attempt the problems. You can download a PDF version by clicking “Make PDF” at the top of the page.
Terms of Use: Please respect the copyright and terms of use displayed on the webpage above.See a broken link? Please let us know!
- Reading: WebElements: “Fluorine,” “Chlorine,” “Bromine,” “Iodine,” and “Astatine”
Links: WebElements: “Fluorine,” “Chlorine,” “Bromine,” “Iodine,” and “Astatine” (HTML)
Note: All the materials above are available in HTML format.
Instructions: Please read these entire webpages. Look on the left-hand side of the page for the “Chemistry and Compounds” heading. In the links under this section, you will find detailed examples of complexes and reactions for each oxygen group metal. These materials also cover subunit 7.7.3.
Terms of Use: Please respect the copyright and terms of use displayed on the webpages above.See a broken link? Please let us know!
- Reading: UC Davis: ChemWiki: “Group 17: The Halogens”
-
7.7.1 Dihalides (i.e., I2, Cl2, etc.)
- Reading: Wikipedia: “Interhalogen”
Link: Wikipedia: “Interhalogen” (PDF)
Instructions: Please read this entire webpage, which provides a description of several heterogenous interhalogens. The section “Summary of Known Interhalogens” offers information on the homogenous interhalogens (F2, Cl2, Br2, and I2).
Terms of Use: The article above is released under a Creative Commons Attribution-Share-Alike License 3.0 (HTML). You can find the original Wikipedia version of this article here (HTML).See a broken link? Please let us know!
- Reading: Wikipedia: “Interhalogen”
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7.7.2 Charge Transfer Properties
Note: Charge transfer properties occur when electrons move from the HOMO (highest occupied molecular orbital) of a donor to the LUMO (lowest unoccupied molecular orbital) of an acceptor. Charge transfers are responsible for many of the colors found in inorganic structures.
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7.7.3 Oxacids and Oxides of Group 7 Elements
- Reading: Everyscience: “Halogen Oxides and Oxo-Acids”
Link: Everyscience: “Halogen Oxides and Oxo-Acids” (HTML)
Instructions: Please read this entire webpage for a listing of halogen oxoacids and examples of halogen oxoacid reactions.
Terms of Use: Please respect the copyright and terms of use displayed on the webpage above.See a broken link? Please let us know!
- Reading: Everyscience: “Halogen Oxides and Oxo-Acids”
-
Final Exam
- Final Exam: The Saylor Foundation's CHEM107 Final Exam
Link: The Saylor Foundation's CHEM107 Final Exam
Instructions: You must be logged into your Saylor Foundation School account in order to access this exam. If you do not yet have an account, you will be able to create one, free of charge, after clicking the link.See a broken link? Please let us know!
- Final Exam: The Saylor Foundation's CHEM107 Final Exam
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