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Purpose of Course

In most engineering classes, you are presented with a set of materials with well-established properties and asked to use the full set of engineering tools at your disposal to design suitable devices and mechanisms for an intended application.  In this course, however, we will learn how to produce materials with properties that have been optimized for a set of desired applications.

To form an accessible view of a very complex world, introductory chemistry and physics courses primarily concentrate on materials and structures in chemical and physical equilibrium.  The equilibrium form of any material is, roughly, a sphere of atoms whose distribution minimizes the free energy of that material.  Because one almost never encounters equilibrium materials, their properties are of little interest in engineering.

Typically, engineering materials are instead highly non-equilibrium assemblages of chemicals that have been carefully combined and distributed in order to constitute a material with a certain set of useful engineering properties.  Consider, for example, carbon steel.  Prepare a piece of steel by adding about 0.5% of carbon into iron at high temperature.  If this material is slowly cooled, it produces a layered structure called pearlite, composed of alternating layers of α-iron and cementite (Fe3C).  The resulting steel is soft and ductile.  However, if the material is rapidly cooled (quenched), the resulting steel forms a highly strained, highly non-equilibrium, body-centered tetragonal crystal structure that is extremely hard and brittle.  These two materials are composed of the same chemical elements in the same proportions; the difference is the material processing.

The theme of obtaining desired engineering properties for a given application through the precise application of processing methods and parameters appears throughout the practice of engineering.  The materials with which we carry out engineering projects are a combination of composition, crystal structure, microstructure, and, in some cases, macroscopic structure.  Most engineers do not practice this set of arcane arts, but all of engineering depends upon the results of such materials optimization.

Consider swords.  For at least 1500 years, the sword was the dominant weapon in most of the world.  But how does one make a fine sword?  Given a little experience with steel, some of the answers become clear.  If you use a low carbon steel, the sword will be tough, but will not take or keep a good edge.  If you instead use a high carbon steel, it will sharpen easily to a fine edge, but will tend to be brittle.  On the other hand, a katana blade (traditional sword of the Samurai) having the same average atomic composition as the high carbon steel blade will sharpen easily, but will also be tough and flexible.

What is different about the blade of a katana?  The katana is composed of thousands of extraordinarily thin layers of steel, generally a few microns in thickness, whose composition alternates between a low carbon steel and an extremely high carbon steel.  The high carbon steel allows the katana to take an extremely sharp edge.  The cutting edge is also self-sharpening to some extent; it cannot become thicker than the blade’s laminations.  In addition, the low carbon steel acts as a strong, tough, and pliable cement between the layers of high carbon steel, thereby giving the blade toughness and flexibility.  The result is one of the finest swords ever made.

The difference between the high-carbon steel blade and the katana is not the overall composition; it is possible to take the atoms from the first and rearrange them to form the katana.  Rather, there is a difference in the local concentration of carbon in the blade, as alternating laminations have large differences in the amount of carbon in their steel.  Does the differing amount of carbon in the laminations result in the superior properties of the katana?  Not alone, no.  There are at least two levels of additional microstructure that must be created through materials processing in order to yield a fine katana blade.  Briefly, the carbon must be convinced to reside in the proper locations in the crystal structure of the iron, and excess carbon that precipitates out of the iron must form a grain structure of the right size.  This additional microstructure is generated by a combination of forging and heat-treating the katana steel.

A raw material can be converted into an engineering material with amazing properties through a carefully controlled series of processing steps.  Materials engineering pivots on these three points: raw material, amazing properties, and the processing that transforms that raw material into an engineering material having those amazing properties.

In this course, we will discuss a wide range of material types, including metals, ceramics, glasses, crystals, polymers, and composite materials.  We will learn about the properties of each of these materials as well as common processing technologies and approaches to optimizing desirable properties.  We will also take a look at some novel materials currently on their way to becoming engineering materials.

Note that this is an upper-division course that requires considerable background in the basic studies of materials and mathematics for success.  The prerequisites for this course include ME101 and ME102, CHEM 101, MA101 and MA102, and PHYS101 and PHYS102.

Preliminary Information

Course Overview Expand Resources Collapse Resources

Unit Outline show close

  • Unit 1: Review - Properties of Materials  

    Materials are the medium in which the art and craft of engineering are practiced.  In order to be successful, an engineer must fully understand the wide variety of material properties that exist and recognize that any of them can spell doom for an engineering application.  For example, it is not harebrained to set out to make a nichrome-heated electrical fuse out of metallic tin; tin is malleable, ductile, and resistant to corrosion and commercial grades of tin have an acceptably low melting point and  suitably low electrical resistivity for use as electrical fuses.  The result is an electrical fuse with very small resistivity that is triggered by an excess of current in a surrounding coil of nichrome wire.  An engineer might design a fuse in this manner to minimize its electrical resistance.  Knowing that impurities increase electrical resistance in a metal, he or she might reasonably make the fuse from very pure tin rather than from a commercial grade of tin. 

    Consider the following scenario: a motor-generator (its fuses included) is built and sent, among other places, to be used outside year-round in Northern Minnesota.  One winter day, a host of complaints rush in (it was a very successful motor-generator).  All of the fuses in the motor-generators in Minnesota have gone bad at nearly the same time!  The motor generators are working fine—they did not cause the fuses to go bad—but the manufacturers’ service department has to check out every single unit.  Is your design to blame?

    Well…yes.  When below roughly 13 oC, tin undergoes a phase transition from the metallic β-tin crystal structure to the nonmetallic α-tin structure, which is an extraordinarily poor electrical conductor.  The transition does not occur in commercial grades of tin, as the impurities prevent the large-scale atomic motions required for this phase transition to take place.  The change to purified tin is the immediate cause of these failures, though the root cause of the failures is not knowing enough about the properties of your materials.

  • 1.1 Strength of Materials  
  • 1.1.1 Elasticity  
  • 1.1.2 Plastic Deformation  
  • 1.1.3 Fracture  
  • 1.1.4 Deformation-Mechanism Maps  
  • 1.2 Phase Transformations  
  • 1.2.1 Phase Diagrams  
  • 1.2.2 Diffusionless Transformations  
  • 1.2.3 Diffusion-Limited Transformations  
  • 1.2.4 Nucleation of Phase Transformations  
  • 1.3 Electrical Properties of Materials  
  • 1.3.1 Resistivity  
  • 1.3.2 Polarizability  
  • 1.3.3 Dielectric Constant  
  • 1.3.4 Band Theory of Solids  
  • 1.4 Magnetic Properties of Materials  
  • 1.4.1 Magnetization  
  • 1.4.2 Magnetic Permeability  
  • 1.4.3 Dia-, Para-, and Ferro-Magnetism  
  • 1.4.4 Magnetic Domains  
  • 1.4.5 Magnetic Hysteresis  
  • 1.5 Optical Properties of Materials  
  • 1.5.1 Reflection and Refraction  
  • 1.5.2 Skin Depth  
  • 1.5.3 Index of Refraction  
  • 1.5.4 Optical Dispersion  
  • 1.5.5 Optical Polarizers  
  • 1.5.6 Optical Interference  
  • 1.5.7 Optical Diffraction  
  • 1.5.8 Optical Scattering  
  • Unit 2: Classes of Engineering Materials  

    Nearly anything can be an engineering material—even a vacuum is an engineering material in old-fashioned vacuum tubes!  There are numerous groups of materials that have similar properties, all of which should be familiar to an engineer.

  • 2.1 Engineering Materials of Antiquity  
  • 2.2 Ferrous Alloys  
  • 2.3 Non-Ferrous Alloys  
  • 2.3 Thermal Protection Barriers  
  • 2.4 Ceramics  
  • 2.5 Electronic Materials  
  • 2.6 Magnetic Materials  
  • 2.7 Polymers  
  • 2.8 Inorganic Polymers (Glasses)  
  • 2.9 Composites  
  • 2.10 Novel Materials  
  • Unit 3: Properties and Processing of Metal Alloys  

    Until rather recently, metal alloys have formed one of the principle groups of materials through which engineering has been developed (the others are ceramics and composites).  The precision with which a metal alloy with a desired microstructure can be formed continues to advance rapidly.

  • 3.1 Dislocations and Precipitates  
  • 3.2 Casting  
  • 3.3 Plastic Deformation  
  • 3.4 Sheet Metal Forming  
  • 3.5 Cutting  
  • 3.6 Machining  
  • 3.7 Welding  
  • 3.8 Heat Treatment  
  • Unit 4: Properties and Processing of Ceramics  

    The earliest ceramics used in engineering were dried or baked clays, which are still widely used in technology.  More recently, modern ceramics have come to play a major role in all fields of engineering.  Ceramics combine strength and toughness with an innate ability to combine favorable characteristics from different base materials.

  • 4.1 Strength of Ceramics  
  • 4.2 Molding  
  • 4.3 Casting  
  • 4.4 Pressing  
  • 4.5 Injection  
  • 4.6 Sintering  
  • 4.7 Nanoceramics  
  • 4.8 Non-Power-Base Ceramic  
  • Unit 5: Properties and Processing of Electronic Materials  

    In this section, we will concentrate on semiconductor-based electronic materials, which are at the heart of most modern electronic devices.  Other classes of electronic materials exist, such as metal wires, quartz crystals, cermet resistors, and many more.  Their respective properties will be treated in the relevant units below.

  • 5.1 Structure of Electronic Materials  
  • 5.2 Growth of Semiconductor Single Crystals  
  • 5.3 Semiconductor Alloys  
  • 5.4 Epitaxial Growth  
  • 5.5 Impurity Doping  
  • 5.6 Metallization  
  • 5.7 Photolithography  
  • 5.8 Heteroepitaxy  
  • 5.9 Amorphous Semiconductors  
  • Unit 6: Properties and Processing of Magnetic Materials  

    Simply put, a magnet is an object that produces a magnetic field that attracts ferromagnetic materials.  Most of the development work done on magnetic materials has been in order to support the production of permanent magnets, which are made from a wide variety of materials and combinations thereof.  Permanent magnet materials are called “hard”—not as a mechanical property, but rather to indicate that the materials permanently retain a large fraction of the magnetization they receive from an external magnetic field.  Hard magnetic materials are often given special properties through heat treatment or by small additions of impurities.    

    Electromagnets also require special classes of materials in order to obtain optimum performance.  The core of an electromagnet is generally made of soft magnetic materials, so that the electrically-generated magnetic field returns to zero when the current to the electromagnet is cut off.  The use of soft magnetic materials is also required for electrical transformers and inductors to function properly.

    A challenge arises when AC current is used to activate an electromagnet.  The magnetic field is strongest in the core material, which, if conducting, will undergo enormous eddy current loss and heating.  This can be avoided by using either laminated magnetic materials (the laminations are insulating and hence avoid eddy current heating by interrupting the flow of eddy currents) or ferrite materials, which are non—conductors of electricity. 

    Finally, superconducting magnets are a special subclass of electromagnets; they provide the largest static magnetic fields accessible to engineers.

  • 6.1 Permanent Magnets  
  • 6.1.1 Metallic Elements  
  • 6.1.2 Hard Ferrites  
  • 6.1.3 Alnico and Ticonal Alloys  
  • 6.1.4 Composite Magnets  
  • 6.1.5 Rare Earth Magnets  
  • 6.1.6 Ultrahigh Temperature Samarium Cobalt Magnets  
  • 6.2 Electromagnets, Transformers, and Inductors  
  • 6.2.1 Iron Alloys  
  • 6.2.2 Laminated Cores  
  • 6.2.3 Soft Ferrite Cores  
  • 6.3 Superconducting Magnets  
  • Unit 7: Properties and Processing of Polymers  

    Nearly unknown to engineers a century ago, polymers have taken on an enormous range of applications that were traditionally left to wood, metal, and glass.  In this unit, we will concentrate on polymers as engineering material in and of themselves.  In Unit 9, we will take a look at the role of polymers in composites.

  • 7.1 Mechanical Behavior of Polymers  
  • 7.2 High-Temperature Properties of Polymers  
  • 7.3 Processing Thermoplastic Polymers  
  • 7.4 Processing Thermoset Polymers  
  • 7.4.1 Injection Molding  
  • 7.4.2 Compression Molding  
  • 7.4.3 Transfer Molding  
  • 7.4.4 Casting  
  • Unit 8: Properties and Processing of Inorganic Glasses  

    Glasses are amorphous solids that are mechanically brittle, non-conductive of electricity, and often capable of passing light.  In this unit, we will cover all glasses that are not metallic or polymeric in nature. 

    Despite the inroads made by plastics, glasses continue to play a major role in engineering.  Glass is widely used in windows, containers, and optics, and can also serve as thermal insulation and structural material in fiber form.  Special types of glass are crucial to the development of long-distance fiber optic networks, as are novel synthesis techniques for such glasses. 

  • 8.1 Is Glass a Solid?  
  • 8.2 Synthesis  
  • 8.2.1 Fusion  
  • 8.2.2 Quenching  
  • 8.2.3 Chemical Vapor Deposition  
  • 8.2.3 Aramid Fiber  
  • 8.2.4 Sol-Gel Techniques  
  • 8.3 Synthesis of Glass-Ceramics  
  • 8.4 Float Plate Method  
  • 8.5 Casting  
  • 8.6 Extrusion  
  • 8.7 Drawing  
  • 8.8 Annealing  
  • 8.9 Grinding and Polishing  
  • Unit 9: Properties and Processing of Polymer-Based Composites  

    Composite materials are generally engineered combinations of multiple constituent materials having complementary physical properties.  The most important natural composite material is wood, which exhibits most of the strengths and weaknesses of all composites.  Adobe is an ancient composite material made of straw and mud, while concrete is a composite of cement, sand, and gravel.  Fiberglass, cultured marble, and even the thermal tiles on the Space Shuttle are composite materials.  In this unit, we will look at polymer-based composite materials, their composition, and their processing.

  • 9.1 Anisotropic Properties – Wood  
  • 9.2 Variety of Fibers  
  • 9.2.1 Glass Fiber  
  • 9.2.2 Carbon Fiber  
  • 9.2.3 Aramid Fiber  
  • 9.3 Fiber-Reinforced Polymers  
  • 9.4 Molding  
  • 9.4.1 Autoclave Molding  
  • 9.4.2 Bag Molding  
  • 9.4.3 Resin Transfer Molding  
  • 9.4.4 Compression Molding  
  • 9.5 Casting  
  • 9.6 Pultrusion  
  • 9.7 Filament Winding  
  • Unit 10: Properties and Processing of Inorganic Composites  

    We will now finish up our treatment of composite materials by examining a range of inorganic composite materials, or materials where both the matrix and the reinforcement materials are inorganic.  These materials are nearly ubiquitous in mechanical engineering applications, both in building materials and in processing equipment.

  • 10.1 Matrix and Reinforcement – Concrete  
  • 10.2 Metal-Matrix Composites  
  • 10.3 Ceramic-Matrix Composites  
  • 10.4 Carbide Tooling  
  • 10.5 Powder Metallurgy  
  • 10.6 Casting  
  • 10.7 Hot Isostatic Pressing  
  • 10.8 Extrusion  
  • 10.9 Diffusion Bonding  
  • 10.10 Unidirectional Solidification  
  • 10.11 Vapor Deposition  
  • 10.12 Melt Infiltration  
  • 10.13 Reactive Processing  
  • Unit 11: Additive Manufacturing  

    Additive Manufacturing is a new frontier in manufacturing technology.  It is defined by ASTM International as “the process of joining materials to make objects from 3D model data, usually layer upon layer, as opposed to subtractive manufacturing methodologies.”

    Additive manufacturing is applicable from the earliest stages of pre-production (rapid prototyping) to production of product.  Certain types of additive manufacturing technologies have the potential to revolutionize tool- and die-making.  The price of additive manufacturing technology is rapidly falling, and 3D printing in particular has become a standard tool in an engineer’s arsenal.

  • 11.1 3D Printing  
  • 11.1.1 Inkjet Printing  
  • 11.1.2 Robocasting  
  • 11.1.3 Ceramic Printing  
  • 11.1.4 Photopolymerization  
  • 11.1.5 Molten Polymer Deposition  
  • 11.1.6 2-Photon Photopolymerization  
  • 11.1.7 Laser Sintering  
  • 11.2 Fully Dense Metallic Prototype Components  
  • 11.2.1 Electron Beam Direct Manufacturing  
  • 11.2.2 Laser Engineered Net Shaping (LENS)  
  • Unit 12: Advanced Materials and Processing  

    The development of novel materials and manufacturing processes is ongoing and rapid.  In this unit, we will examine several of the hottest advances in engineering materials.

  • 12.1 Aerogels  
  • 12.2 Metal and Ceramic Foams  
  • 12.4 Carbon-Carbon Composites  
  • 12.5 Amorphous Metals  
  • 12.6 Hydrogen Storage Systems  
  • 12.7 High-Temperature Superconductors  
  • 12.8 Carbon Nanotubes and Graphene  
  • 12.9 Synthesis of Quantum Nanodots  
  • 12.10 Ferrofluids and Magnetorheological Fluids  

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